Hybrid ac/dc microgrid clusters are key building blocks of smart grid to support sustainable and resilient urban power systems. Practically, in networked microgrid clusters, the subgrid load-priorities and power quality requirements for different areas vary significantly. In order to realize optimal power exchanges among microgrid clusters, this chapter proposes a decentralized self-optimizing power control scheme for interlinking converters (ILCs). First, a priority-driven optimal power exchange model of ILCs is built that fully considers the priorities and capacities in subgrids. The whole optimization objective is to minimize the total dc-voltage/ac-frequency state deviations of subgrids. Second, to realize the decentralized power flow control, an optimal-oriented quasi-droop control strategy of ILCs is introduced. Consequently, as each of ILCs only monitors the local ac-side frequency and dc-side voltage signals, the whole optimal power control of the wide-area microgrid clusters is achieved in a decentralized manner without any communication link. Thus, the proposed control algorithm has the features of decreased cost, increased scalability, reduced geographic restrictions and high resilience and robustness in terms of communication faults. Finally, the proposed method is validated by three cases in hardware-in-loop environment.