Hydride Vapor Phase Epitaxy Method
摘要
In the 1960s, halide-based vapor phase epitaxy technology was developed for the growth of Ge (Marinace in IBM J Res Dev 4:248–255, 1960), GaAs (Knight et al. in Solid-State Electron 8:178–0, 1965) and GaP (Oldham in J Appl Phys 36:2887–3000, 1965) materials; based on this, the growth of GaAs, GaP materials was also achieved in a sealed chamber using HCl gas as the reaction precursor (Moest and Shupp in J Electrochem Soc 109:1061–1065, 1962), which is the prototype of contemporary hydride vapor phase epitaxy (HVPE) growth technology. In 1966, J. J. Tietjen and J. A. Amick from the RCA laboratory further used HCl and metal Ga reaction as the group III source, and arsine and phosphine as the group V source, to achieve the growth of GaAsxP1−x materials (Tietjen et al. in J Electrochem Soc 116:492–0, 1969), marking the rapid development period of HVPE growth technology.