This review synthesizes the existing literature on the use of virtual reality (VR) technology to investigate the impact of natural environments on human restoration. Natural environments, such as forests, parks, and green spaces, are widely recognized for their positive effects on mental health and well-being. However, urbanization has limited regular access to these environments for many individuals. As an emerging tool, VR technology offers an alternative means for individuals to experience nature virtually. This review explores the current capabilities of VR in simulating natural environments to promote psychological restoration, highlights the technical characteristics of VR systems, and employs bibliometric analysis to trace the field’s historical development and future trends through keyword temporal development maps. Moreover, it addresses experimental design and evaluation methods, focusing on the impact of three common types of natural environments on restoration outcomes, and identifies potential avenues for future research. Finally, the review discusses the advantages, limitations, and future prospects of VR applications in the context of restoration.