In recent years, the evolution of additive manufacturing technologies has revolutionized various industries, particularly in the area of photoelectric devices. This chapter explores the transformative potential of 3D, 4D, and 5D printing technologies in developing and fabricating advanced photoelectric devices. The principles of layer-by-layer deposition in additive manufacturing techniques offer unparalleled flexibility, precision, and scalability in the production of intricate structures with tailored functionalities. Initially, this chapter provides a comprehensive overview of traditional photoelectric device fabrication techniques and their inherent limitations, giving way to the introduction of additive manufacturing as a disruptive alternative. Subsequently, it investigates the fundamentals of 3D printing, explaining the underlying processes of additive manufacturing. Through precise control of material deposition, layer thickness, and geometry, 3D printing enables the creation of complex photoelectric device architectures with enhanced efficiency and performance. Furthermore, the narrative progresses to discuss the emerging frontier of 4D printing, wherein materials possess the ability to alter their shape, properties or functionality in response to external stimuli over time. Moreover, the exploration extends to the promising area of 5D printing which transcends the physical dimensions of space and time by embedding the additional information within the printed objects. With the advances in nanotechnology and material science, 5D printing fills the photoelectric devices with unprecedented functionalities such as multi-spectral absorption, tuneable bandgaps, and enhanced light-trapping capabilities. The encoding of intricate nanostructures and metamaterial architectures, 5D printing enables the realization of next-generation photonic devices with unparalleled performance metrics.