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Domino reactions are intramolecular reactions in which a single event triggers the conversion of a starting material to a product, which then provides a substrate for the next reaction until a stable final product is obtained (Fig. 4.1a) (Tietze in Chem. Rev. 96:115–136, 1996; L. F. Tietze, Domino Reactions: Concepts for Efficient Organic Synthesis., Wiley (2014);Nicolaou et al. in Chem. Commun. 3:551–564, 2003;Nicolaou et al. in Angew. Chem. Int. Ed. 45:7134–7186, 2006;Enders et al. in Angew. Chem. Int. Ed. 46:1570–1581, 2007;Grossmann and Enders in Angew. Chem. Int. Ed. 51:314–325, 2012;Pellissier in Adv. Synth. Catal. 354:237–294, 2012; R. Westphal, E. Venturini Filho, F. Medici, M. Benaglia, S. J. Greco, Synthesis (Stuttg). 54, 2927–2975 (2022);). They have contributed greatly to green chemistry such as by improving the reaction efficiency (atom economy) and simplifying the workup process, thanks to the generation of multiple bonds in a single step.

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Domino-Redox Reaction Induced by a Conformational Change Based on Dithiin Bisquinodimethane Skeleton

  • 章节

  • 发表日期：

    2025年

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  • Takashi Harimoto

摘要

Domino reactions are intramolecular reactions in which a single event triggers the conversion of a starting material to a product, which then provides a substrate for the next reaction until a stable final product is obtained (Fig. 4.1a) (Tietze in Chem. Rev. 96:115–136, 1996; L. F. Tietze, Domino Reactions: Concepts for Efficient Organic Synthesis., Wiley (2014);Nicolaou et al. in Chem. Commun. 3:551–564, 2003;Nicolaou et al. in Angew. Chem. Int. Ed. 45:7134–7186, 2006;Enders et al. in Angew. Chem. Int. Ed. 46:1570–1581, 2007;Grossmann and Enders in Angew. Chem. Int. Ed. 51:314–325, 2012;Pellissier in Adv. Synth. Catal. 354:237–294, 2012; R. Westphal, E. Venturini Filho, F. Medici, M. Benaglia, S. J. Greco, Synthesis (Stuttg). 54, 2927–2975 (2022);). They have contributed greatly to green chemistry such as by improving the reaction efficiency (atom economy) and simplifying the workup process, thanks to the generation of multiple bonds in a single step.