Large Language Models show great potential with external tools, but face significant challenges in complex, multi-turn tool invocation. They often exhibit weak planning, tool hallucination, erroneous parameter generation, and struggle with robust interaction. To tackle these issues, we present PEARL, a novel framework to enhance LLM planning and execution for sophisticated tool use. PEARL adopts a two-stage approach: an offline phase where the agent explores tools to learn valid usage patterns and failure conditions, and an online reinforcement learning phase. In the online phase, a dedicated Planner is trained via group Relative Policy Optimization (GRPO) with a carefully designed reward function that provides distinct signals for planning quality. Experiments on the ToolHop and T-Eval benchmarks show PEARL significantly outperforms existing methods, achieving a new state-of-the-art success rate of 56.5% on ToolHop while maintaining a low invocation error rate. Our work marks a key advance in addressing the complex planning challenges of tool use, contributing to the development of more robust and reliable LLM-based agents.