The development of renewable zero-carbon fuels contributes to industrial decarbonization, and ammonia as a chemical and agricultural product has attracted attention due to its high energy density and carbon-free properties. In this paper, the mainstream ammonia combustion mechanisms in recent years are evaluated in detail, and a multi-dimensional mechanism evaluation system is established using statistical methods. In order to make the results more accurate, as many experimental data as possible are selected for cross-validation. Finally, the recommended mechanisms for ammonia and ammonia-hydrogen mixtures are given for the prediction of ignition delay time and laminar burning velocity.

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Multi-dimensional Evaluation of Chemical Kinetic Mechanisms for Ammonia and Ammonia/Hydrogen Combustion

  • Chaowei Ge,
  • Fang Chen,
  • Leilei Xu,
  • Kai Zhang,
  • Christophe Duwig

摘要

The development of renewable zero-carbon fuels contributes to industrial decarbonization, and ammonia as a chemical and agricultural product has attracted attention due to its high energy density and carbon-free properties. In this paper, the mainstream ammonia combustion mechanisms in recent years are evaluated in detail, and a multi-dimensional mechanism evaluation system is established using statistical methods. In order to make the results more accurate, as many experimental data as possible are selected for cross-validation. Finally, the recommended mechanisms for ammonia and ammonia-hydrogen mixtures are given for the prediction of ignition delay time and laminar burning velocity.