From the knowledge of thermodynamics, it is known that if a system is in equilibrium, the Gibbs free energy of the system is minimal, and the equilibrium phase in the system is called the stable phase, if the system is in a metastable state, the phase at this time is called the metastable phase. The system has a tendency to transition from a non-equilibrium state to an equilibrium state, so the metastable phase also has a tendency to transition to the stable phase.

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Nucleation of Crystals

  • Qudong Wang,
  • Nannan Zhang

摘要

From the knowledge of thermodynamics, it is known that if a system is in equilibrium, the Gibbs free energy of the system is minimal, and the equilibrium phase in the system is called the stable phase, if the system is in a metastable state, the phase at this time is called the metastable phase. The system has a tendency to transition from a non-equilibrium state to an equilibrium state, so the metastable phase also has a tendency to transition to the stable phase.