Large language models (LLMs) excel in text understanding and generation but raise significant safety and ethical concerns in high-stakes applications. To mitigate these risks, we present Libra-Guard, a cutting-edge safeguard system designed to enhance the safety of Chinese-based LLMs. Leveraging a two-stage curriculum training pipeline, Libra-Guard enhances data efficiency by employing guard pretraining on synthetic samples, followed by fine-tuning on high-quality, real-world data, thereby significantly reducing reliance on manual annotations. To enable rigorous safety evaluations, we also introduce Libra-Test, the first benchmark specifically designed to evaluate the effectiveness of safeguard systems for Chinese content. It covers seven critical harm scenarios and includes over 5,700 samples annotated by domain experts. Experiments show that Libra-Guard achieves 86.79% accuracy, outperforming Qwen2.5-14B-Instruct (74.33%) and ShieldLM-Qwen-14B-Chat (65.69%), and nearing closed-source models like Claude-3.5-Sonnet and GPT-4o. These contributions establish a robust framework for advancing the safety governance of Chinese LLMs and represent a tentative step toward developing safer, more reliable Chinese AI systems. Dataset & Model: huggingface.co/collections/caskcsg/Libra   github.com/caskcsg/Libra/tree/main/Libra