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Chemical Thermodynamics

  • Martin Dehli

摘要

In section 12, technically important chemical reactions are dealt with in tasks: e.g. the synthesis of water gas, the complete combustion of propane, the reaction of hydrogen with oxygen, the synthesis of ammonia from hydrogen and nitrogen as well as the reforming of methane with water vapor. The tasks show, for example, the calculation of the temperature-dependent quantities molar enthalpy of reaction, molar entropy of reaction and molar free enthalpy of reaction as well as the determination of the physical norm volume-related quantities upper calorific value and the lower calorific value. The composition of the mixture of ideal gases (educts and products) is also calculated for a certain reaction depending on the degree of reaction. Furthermore, one task deals with the determination of the exergy loss at the complete combustion of methane.