Access to electricity is a necessary, if not sufficient, element for poverty alleviation, social inclusion, and economic growth in Africa. Though the share of people with access to electricity at the global level has steadily increased, countries in the CAR and SSA still face significant challenges in reaching energy access. The electrification landscape in Africa shows a paradox of abundant energy resources alongside widespread energy poverty. The electrification gap in Africa is uneven, with stark disparities along geographic, socioeconomic, and demographic lines. The evidence indicates that Africa’s electricity sector faces a trilemma of challenges: financing, policy, and affordability. As a multifaceted tool, electrification impacts individuals and economies through various sectors such as economic productivity, education, health, gender equality, and social inclusion. Electrification influences development at both microeconomic and macroeconomic levels. While ongoing rural electrification enables the use of powered irrigation pumps, extending farming seasons beyond rain-fed agriculture, it has also replaced many polluting and inefficient light sources like kerosene lamps across communities in Africa. Finally, electrification reduces the time burden of domestic chores, a task disproportionately assigned to women and girls, and provides lighting for students. This has a significant effect on educational and health outcomes. Africa therefore needs a sustainable energy justice plan that includes proactive measures such as gender-sensitive product design, inclusive governance of community energy systems, and targeted financing for all citizens.