Optimisation of Steam Recovery from Calcination and the Bayer Circuit Using Multi-stage Mechanical Vapour Recompression
摘要
The present study evaluates the technical and economic feasibility of recovering vented vapour from the Bayer circuitBayer circuit (evaporation, precipitation, and digestionDigestion steps) and calcinationCalcination as a decarbonisation strategy for aluminaAlumina refining, using Aspen Plus, compared with conventional natural gas boilers. Results show that 100% of steam supply for Bayer circuitBayer circuit usage can potentially be met via internal recovery: 43% from calcinationCalcination (H2 in oxygen‑steam combustion), 9% from digestionDigestion, 37% from evaporation, and 11% from precipitation. An estimated 79% reduction in energy consumptionEnergy consumption for steam supply is plausible with full (100%) steam recoverySteam recovery, relative to steam generation from gas boilers. Economically, compared with boilers at a gas price of 7.5 US$/GJ including a cost of carbon capture and storage (CCSCarbon Capture and Storage (CCS)) of 179 US$/tCO2, the full steam recoverySteam recovery scenario is estimated to reduce the levelised cost of decarbonised steam for the Bayer circuitBayer circuit (LCOSB) by 50% at a fixed 70 US$/MWh electricity price, dropping from 110.2 to 55.1 US$/tAl2O3. The capital cost of multi-stage mechanical vapour recompression (MVR) is the dominant component (50%) of the LCOSB in this scenario, while renewable electricity remains the primary operating cost driver. A sensitivity analysis indicates that, with natural gas at 7.5 US$/GJ and no CCSCarbon Capture and Storage (CCS), cost parity is achieved when electricity prices fall below 60 US$/MWh; with CCSCarbon Capture and Storage (CCS), electricity-based steam recoverySteam recovery is cost-competitive for costs above 30 US$/MWh.