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On cooling, a molten polymer may undergo either crystallisation (route a) or a transition into a glass (i.e. a frozen, amorphous liquid) according to route b. These two possibilities are displayed in the specific volume-temperature diagram of Fig. 5.1. The glass transition involves a change in the slope in the specific volume temperature plot (route b).

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The Glassy Amorphous State

  • 章节

  • 发表日期：

    2025年

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  • Ulf W. Gedde,
  • Mikael S. Hedenqvist,
  • Mats Johansson,
  • Lars Berglund,
  • Jakob Wohlert

摘要

On cooling, a molten polymer may undergo either crystallisation (route a) or a transition into a glass (i.e. a frozen, amorphous liquid) according to route b. These two possibilities are displayed in the specific volume-temperature diagram of Fig. 5.1. The glass transition involves a change in the slope in the specific volume temperature plot (route b).