Selective Hydrometallurgical Separation of Ni and Co from Cu–Ni Matte for Battery Materials Production
摘要
The growing demandDemand for electric vehiclesElectric Vehicles (EVs) has significantly increased the need for Ni and Co, essential components in batteriesBattery. A novel hydrometallurgical processHydrometallurgical processes has been developed to selectively recover Ni and Co from Cu–Ni matteMatte containing approximately 71.3% Cu, 6.1% Ni, 0.2% Co, and minor impurities like Fe, primarily as sulfides. Selective atmospheric leachingLeaching with HCl and H2O2 was employed to extract Ni and Co, leaving most of Cu as a leach residue that can be a potential feedstock for Cu refinersFeedstock for Cu refiners. Residual Cu was removed by cementation, followed by precipitationPrecipitation to eliminate Fe and other impurities, achieving over 99% separation of Cu and Fe with minimal Ni loss (approximately 2%). In the final step, carbonation with Na2CO3 precipitated Ni as NiCO3NiCO3 under optimal conditions (pH 7.5, 60 °C), meeting battery materialBattery materials specifications.