The integration of renewable energy into sustainability metrics is essential for achieving the Sustainable Development Goals (SDGs), particularly in regions aiming to balance energy efficiency, waste management, and urban development. This study explores the application of multicriteria decision-making and statistical techniques to evaluate municipal sustainability, with a focus on renewable energy, using the Alto Minho region of Portugal as a case study. The analysis incorporates 12 SDG indicators across ten municipalities, addressing energy consumption, urban renewal, and waste management. Cluster analysis revealed distinct groups of municipalities, highlighting disparities in sustainability performance. Municipalities such as Melgaço and Monção excelled in energy-related metrics, while others showed strengths in waste management and urban renewal. The Analytic Hierarchy Process (AHP) emphasized the importance of renewable energy indicators, revealing notable changes in rankings when energy-related criteria were prioritized. Ponte de Lima and Melgaço ranked highest under energy-focused weighting schemes, showcasing their leadership in energy efficiency and renewable adoption. The findings underscore the need for targeted policies to enhance sustainability across municipalities, particularly in regions lagging in energy performance.