Modeling of Nitric Oxide (NO) vibrational states in hypersonic reentry flows is necessary to interpret emission and absorption spectra. To that end, the vibrational relaxation number, \(Z_v^C\) , is an important parameter in the Larsen-Borgnakke (LB) model which is used to express vibrational relaxation rates for collisions. In this work, we use rates obtained from Quasi-Classical Trajectory (QCT) calculations of Andrienko et al. [2] for the NO-O vibrational relaxation process to arrive at a new fit for the \(Z_v^C\) parameter. This new fit for \(Z_v^C\) is implemented in Direct Simulation Monte Carlo (DSMC) calculations for the case of hypersonic flow over a cylinder where the effect of the new fit on NO macroparameters and vibrational state populations is studied.

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Calibration of the Larsen-Borgnakke Model for NO-O Vibrational Relaxation

  • Shubham Thirani,
  • Deborah A. Levin,
  • Ingrid J. Wysong

摘要

Modeling of Nitric Oxide (NO) vibrational states in hypersonic reentry flows is necessary to interpret emission and absorption spectra. To that end, the vibrational relaxation number, \(Z_v^C\) , is an important parameter in the Larsen-Borgnakke (LB) model which is used to express vibrational relaxation rates for collisions. In this work, we use rates obtained from Quasi-Classical Trajectory (QCT) calculations of Andrienko et al. [2] for the NO-O vibrational relaxation process to arrive at a new fit for the \(Z_v^C\) parameter. This new fit for \(Z_v^C\) is implemented in Direct Simulation Monte Carlo (DSMC) calculations for the case of hypersonic flow over a cylinder where the effect of the new fit on NO macroparameters and vibrational state populations is studied.