A brief history of the development and utility of hybridizationHybridization theory and valence bond theoryValence bond theory is presented. Qualitative reasons and a simple mathematical model are offered as to why the assertion of sp3 hybridizationSp-hybridization in methane and isoelectronicIsoelectronic species is not correct. Nonetheless, we acknowledge that simple hybridization is a convenient way when looking at the bonding in molecules.

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Although sp3 Hybridization is Not Found for the Carbon in Methane Nor in Isoelectronically Related Species, the Concept of Hybridization is Still Useful and Powerful

  • Martin Pomerantz,
  • Isaiah M. Borkowski,
  • Kathleen F. Edwards,
  • Zelek S. Herman,
  • Shayan Khan,
  • Joel F. Liebman

摘要

A brief history of the development and utility of hybridizationHybridization theory and valence bond theoryValence bond theory is presented. Qualitative reasons and a simple mathematical model are offered as to why the assertion of sp3 hybridizationSp-hybridization in methane and isoelectronicIsoelectronic species is not correct. Nonetheless, we acknowledge that simple hybridization is a convenient way when looking at the bonding in molecules.