Chronic wounds pose a significant healthcare challenge globally, necessitating innovative solutions to improve healing outcomes. Biomaterials and additive manufacturing (AM) have emerged as promising technologies in this context. This chapter explores the synergistic potential of biomaterials and AM in the development of advanced wound care products. Firstly, it discusses the distinctive properties of biomaterials that make them appropriate for wound healing applications, such as biocompatibility, bioactivity, and tunable degradation profiles. Secondly, it delves into the capabilities of AM techniques, including 3D printing and bioprinting, in fabricating customized wound dressings and scaffolds with precise geometries and controlled porosities. Moreover, the chapter reviews recent advancements in biomaterial design tailored for chronic wound healing, highlighting case studies where applicable. It also addresses challenges such as scalability, regulatory considerations, and clinical translation of biomaterial-based AM products. In conclusion, this chapter underscores the transformative potential of integrating biomaterials and AM technologies to revolutionize chronic wound care, paving the way for personalized, efficient, and effective treatment strategies.