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The definition of thermal average values in the canonical ensemble given in ( 1.86 ) as a sum over all states with a Boltzmann factor as the weight is rigorous. It is also useful, insofar as the levels and their degeneracies can be calculated quantum mechanically.

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The Relation Between Classical and Quantum Statistics

  • 章节

  • 发表日期：

    2025年

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  • Klavs Hansen

摘要

The definition of thermal average values in the canonical ensemble given in ( 1.86 ) as a sum over all states with a Boltzmann factor as the weight is rigorous. It is also useful, insofar as the levels and their degeneracies can be calculated quantum mechanically.