Based on the impact of electricity price on the economic operation of the system, considering the impact of time-of-use electricity price collaborative dispatch and demand-side response on the economy of hydrogen-containing energy storage systems, the time-of-use electricity price is used as the decision variable, and customer satisfaction is the auxiliary adjustment variable to establish the demand side The load response characteristic curve of the responsive hydrogen-containing microgrid system; analyze and solve the optimal time-of-use electricity price after adopting the demand-side response strategy, providing a basis for the real-time electricity price of the microgrid. The simulation results show that the electricity price collaborative dispatch optimization model based on the hydrogen-containing composite energy storage system can improve user satisfaction while reducing operating costs and optimizing system benefits.