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Dynamic Processes and Chemical Exchange in OxP Derivatives

  • Václav Březina

摘要

Systems of oxoporphyrinogen hosts in the presence of organic acids (chiral CSA or achiral DFA) show not only dynamic host-guest binding (described in the previous chapter) but also other processes such as rotation of bulky side groups. In this chapter, these processes are described qualitatively and some of them even quantitatively using appropriate models.