Quantitative Description of Supramolecular Binding
摘要
Supramolecular structures encompass molecular assemblies without formation of covalent bonds. The assemblies are held together by hydrogen bonding or by electrostatic forces. These weak binding forces enable incessant formation and dissociation of the supramolecular complex, implying that the supramolecular systems are dynamic even after they achieve equilibrium. Formation and dissociation of supramolecular complexes follow the general laws of kinetics and equilibrium for chemical reactions, which are explained in this chapter.