Modeling of the Correction to the Interphase Energy for the Polarization of Surface Ions at the Cesium-Nonpolar Organic Liquid Boundary

Recently, there has been an increase in the number of research works on the synthesis and investigation of the properties of metal-organic frame structures. This is due to the possibility of wide practical application of these materials in many industries. Of particular interest is the possibility of their use in the targeted delivery of drugs, and for the production of compounds in which there are inclusions exhibiting quantum properties. When obtaining metal-organic frame structures, it is possible to set the necessary properties due to the ability to vary both the elemental composition in metal centers and the composition and length of organic molecules connecting these metal centers. In this regard, the relevance of understanding the nature of the interaction of metals with organic compounds arises. In this paper, within the framework of a modified version of the electron-statistical theory, a correction is obtained for the polarization of metal ions of the transition layer and the polarization of the liquid in the field of a semi-infinite metal to the interphase energy at the boundary of the faces of cesium crystals with nonpolar organic liquids. The dependence of the correction to the interphase energy for polarization on the macroscopic permittivity of the liquid is established. The orientation dependence of the polarization correction is obtained. It is shown that the polarization of metal ions and organic liquid reduces the interfacial energy and decrease in magnitude with an increase in the dielectric constant of the liquid.