Diversity Oriented Synthesis of Metal-Organic Frameworks
摘要
Metal‒Organic Frameworks (MOFs) are an emerging class of novel porous materials bearing unique high surface area and structural tunability. Post-synthetic functionalization plays a pivotal role not only in facilely diversifying MOF structures but also in meeting the requirement in practical applications. Herein, we explore the utility of diversity oriented synthesis (DOS) in the MOF field, summarizing the various post-synthetic modifications and pore engineering techniques and discussing how they regulate the pore environment and sizes of MOFs.