This book chapter presents the results of a systematic review that explored the role of artificial intelligence (AI) in promoting access to clean energy in Africa from previous studies. Drawing insights from high-quality studies, the research provides a comprehensive overview of AI’s multifaceted impact on energy access across the continent. It connects to this book collection by examining how AI, a cutting-edge technological field often researched within universities, can be leveraged to enhance clean energy access in Africa. This aligns with the book’s focus on climate change solutions, as promoting clean energy is a critical component of global efforts to mitigate climate change. The investigation covered critical dimensions: AI technologies, such as smart grids, digitalization, machine learning algorithms, blockchain, and smart metering, played a substantial role in enhancing energy access. They facilitated energy decentralization, improved energy resource management, and contributed to cleaner and more reliable energy access. Despite these benefits, the study identified challenges in adopting AI in African countries, including financial constraints, policy limitations, technical complexities, and data management issues. These obstacles require supportive policy frameworks, capacity-building initiatives, and innovative financing mechanisms. The research also emphasized the significant environmental implications of AI-driven clean energy initiatives in Africa, showcasing how AI technologies can optimize energy consumption and promote renewable energy sources. The chapter contributes to the discourse by highlighting AI’s potential in transforming energy systems, a key area of interest for educational and research initiatives on climate change. The findings contribute to the academic discourse, providing actionable insights for stakeholders. They underscore the transformative potential of AI technologies in addressing energy access challenges on the continent and signify a major advancement on the journey toward energy justice for a brighter and cleaner energy future in Africa.