The use of visible light-driven photocatalysis has risen to prominence, offering an efficient and cost-effective synthetic strategy for accessing a broad spectrum of radical species and intermediates. This method also allows for efficient control over the stereoselectivity of reactions, when merging with asymmetric catalysis under mild conditions. On the other hand, the catalytic asymmetric construction of axially chiral heterocyclic compounds has emerged as a burgeoning field of study. This is attributable to their ubiquitous occurrence in natural products, bioactive molecules, advanced materials, and their role as chiral ligands and catalysts. With the advancement of photochemistry, the application of visible light-driven reactions for the synthesis of axially chiral heterocyclic compounds has recently garnered considerable interest. In this chapter, we provide a comprehensive summary and highlight the latest advancements in this rapidly developing area, focusing particularly on the elucidation of reaction mechanisms and the exploration of substrate versatility.