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This chapter delves into the emerging role of bismuth cations as catalysts in various chemical reactions, highlighting their unique properties and versatility. Bismuth, a heavy metal with low toxicity, has garnered attention for its effective catalytic performance, particularly in organic transformations. This work is a comprehensive compilation of bismuth monocations and dications reported to date, detailing their synthesis, catalytic activity, substrate scope, limitations and mechanistic perspective.

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Cationic Bismuth Compounds in Catalysis

  • 章节

  • 发表日期：

    2025年

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  • Annabel Benny,
  • Ajay Venugopal

摘要

This chapter delves into the emerging role of bismuth cations as catalysts in various chemical reactions, highlighting their unique properties and versatility. Bismuth, a heavy metal with low toxicity, has garnered attention for its effective catalytic performance, particularly in organic transformations. This work is a comprehensive compilation of bismuth monocations and dications reported to date, detailing their synthesis, catalytic activity, substrate scope, limitations and mechanistic perspective.