Organometallic Nanoparticles for Magnetically Induced Catalysis in Solution
摘要
In the starting exploration of magnetically induced catalysis, organometallic nanoparticles (NPs) have proven themselves to serve as efficient and versatile heating agents, demonstrating remarkable potential for diverse liquid-phase reactions. The present chapter delves into the synthesis and application of various organometallic magnetic NPs (MagNPs), i.e., Fe2.2C, FeCo, FeNi3, and NiCo NPs. These magnetic cores, decorated with metals like Ru, Cu, or Ni, exhibit remarkable performance in hydrogenation and hydrodeoxygenation reactions, with promising results in the valorization of biomass derivatives under low hydrogen pressures. The superior catalytic activity compared to those achieved under similar apparent conditions through conventional heating, as well as some recent advances in stability, add to the well-proven advantages of this technology, such as rapid heating, improved energy efficiency, and adaptability to renewable energy sources. The present chapter also establishes the need for precise temperature control, optimized ligand strategies, and strategic stability enhancement in aqueous media, signaling avenues for future progress in magnetically induced catalysis.