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Gravity-Assisted SHS Metallurgy of Cast High-Entropy Mo–Nb–Ta–(Cr,V,Zr,Hf) Alloys

  • V. N. Sanin,
  • D. M. Ikornikov,
  • A. O. Sivakova,
  • D. Yu. Kovalev,
  • O. A. Golosova

摘要

Abstract

Cast Mo–Nb–Ta–(Cr,V,Zr,Hf) refractory high-entropy alloys were first prepared via gravity-assisted SHS metallurgy. It was shown that the ingots crystallize from the liquid state, in which a homogeneous distribution of constituting elements is provided. The phase composition of synthesized RHEA ingots was revealed to be doped component dependent. Combined reduction of metals of V (Nb, Ta, V) and VI (Cr, Mo) groups formed single-phase alloys with a bcc crystal structure. MoNbTaCr alloys doped with Zr or Hf having hexagonal crystal structure were found to consist of fcc and hcp phases in addition to bcc solid solution.