Abstract <p>In this work, the main characteristics of the crystal–homogeneous phase transition in argon are calculated on the basis of the correlation cell-cluster expansion. Along the crystallization and melting line, the heat capacity at constant pressure is calculated for the crystalline phase and for the homogeneous phase. A monotonic decrease of the heat capacity at constant pressure with increasing temperature is observed. A comparison between theoretical data and experimental results is carried out, showing good agreement.</p>

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Heat Capacity at Constant Pressure along the Crystallization and Melting Line of Argon

  • P. N. Nikolaev

摘要

Abstract

In this work, the main characteristics of the crystal–homogeneous phase transition in argon are calculated on the basis of the correlation cell-cluster expansion. Along the crystallization and melting line, the heat capacity at constant pressure is calculated for the crystalline phase and for the homogeneous phase. A monotonic decrease of the heat capacity at constant pressure with increasing temperature is observed. A comparison between theoretical data and experimental results is carried out, showing good agreement.