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Abstract <p>A novel mechanism has been discovered for the phototransformations of methyl formate radical cations (RCs) wherein an RC that is furnished upon thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the bridging oxygen atom undergoes photoinduced H<sup>+</sup> transfer to the matrix.</p>

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Photochemistry of Methyl Formate Radical Cations in Frozen CFCl3 Matrices

  • 期刊论文

  • 发表日期：

    2025年4月1日

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  • M. Ya. Melnikov,
  • O. I. Gromov,
  • V. I. Pergushov,
  • D. A. Pomogailo,
  • I. D. Sorokin

摘要

Abstract

A novel mechanism has been discovered for the phototransformations of methyl formate radical cations (RCs) wherein an RC that is furnished upon thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the bridging oxygen atom undergoes photoinduced H+ transfer to the matrix.