Phosphate electrosorption using layered double hydroxides–carbon composites: Adsorption isotherms and energy recovery studies
摘要
Rice husk activated carbon and Mg/Fe-layered double hydroxides (LDHs) were synthesized using double-crucible and co-precipitation methods, and the material was utilized in the electrosorption of phosphorus. SEM analysis revealed smaller LDH particle sizes with higher magnesium ratios. The activated carbon synthesized at 650 °C showed well-developed mesopores and nanopores. XRD indicated that LDH crystallinity increased with magnesium content. Phosphate electrosorption was optimized using an Mg/Fe ratio of 2:1 mixed with activated carbon, achieving maximum removal at 1.5 V. Electrosorption followed the Langmuir isotherm, with a maximum capacity of 151.51 mg/g. Regeneration tests demonstrated energy recovery, with electrodes desorbing phosphate at 0.94 V. These findings demonstrate the potential of the material for sustainable water treatment and agricultural applications.
Graphical abstract