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Toward thermally stable Ni(GeSn) contacts using pre-amorphization by implantation or nanosecond laser annealing

  • Andrea Quintero,
  • Marianne Coig,
  • Frédéric Mazen,
  • Pablo Acosta-Alba,
  • Jean-Michel Hartmann,
  • Patrice Gergaud,
  • Vincent Reboud,
  • Philippe Rodriguez

摘要

Ni-based metallization for GeSn devices provides high-quality contacts with low sheet and contact resistances. However, the Ni/GeSn system has a major drawback: its poor thermal stability due to NiGe agglomeration and Sn segregation above 350 °C. This study focuses on two different process options, namely, pre-amorphization by implantation (PAI) and UV nanosecond laser annealing (UV-NLA), to improve the thermal stability of Ni(GeSn) alloys. We have shown that the use of C-PAI or UV-NLA has a positive effect on the Ni(GeSn) morphology and helps to delay Sn segregation and NiGe agglomeration phenomena. This is a major advance in thermally stable Ni-based contacts on GeSn.

Graphical abstract