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Modelling reaction transfer velocities in disconnected compact heterogeneous multilayer reactive material systems

  • Deepshikha Shekhawat,
  • Kashish Sindhani,
  • Vishal A. Raheja,
  • Mostafa Baloochi,
  • Nishchay A. Isaac,
  • Jörg Pezoldt

摘要

The tuning of the self-propagating reaction is studied theoretically by introducing a non-reactive material between two reactive material elements. For the study, the Ni/Al bilayer system was chosen. The Ni/Al elements were placed on a silicon wafer covered with a 1-µm-thick silicon dioxide. The spaces between the multilayer reactive material elements were filled with different non-reactive materials covering a wide range of thermal properties. On top of this heterogeneous layer, a 1-µm-thick sealing layer was placed consisting of the filler material. The carried out two-dimensional simulations demonstrated that embedding material allows to scale the ignition transfer time and the heat propagation velocity. For example, for a transfer length of 1 µm, the ignition time can be tuned from nano- to microseconds. Consequently, in contrast to previous results embedding materials allow scaling the properties of the self-propagating reaction in heterogeneous reactive material systems.

Graphical abstract