Detection of copper in plants and soil with electrochemically reduced graphene oxide–carbon cloth sensors
摘要
Copper (Cu2+) is a vital nutrient in the growth of certain plants. Thus, it is important to monitor the concentration of copper in agriculture. Electrochemically reduced graphene oxide (ERGO) was electrodeposited on an inexpensive, flexible carbon cloth (CC) substrate, and the deposition process was optimized for voltammetric detection of Cu2+. The resulting ERGO-CC sensors were used to quantify CuSO4 concentrations down to 9 nM (S/N > 3), while the ERGOon glassy carbon electrode could detect down to 7 nM (S/N > 3). The sensors detected copper from real samples and in the presence of other potentially interfering compounds contained in fertilizers.
Graphical abstract