<p>This study explores the fabrication and characterization of MgAgSb thermoelectric composites to optimize performance through nanoparticle engineering and contact material selection. Adjusting the Mg<sub>3</sub>Sb<sub>2</sub> to Ag<sub>3</sub>Sb nanopowder molar ratio to 2:1 reduced redundant Ag<sub>3</sub>Sb phases, which significantly enhancing thermoelectric efficiency. The effects of contact metals, including Al, Ag, and Ni, were evaluated using fabrication methods such as paste application, cold pressing, foil, and sputtering, showing their impact on the Seebeck coefficient. These results highlight the critical role of material composition and contact engineering in advancing thermoelectric materials. This approach provides a cost-effective strategy to improve MgAgSb composites in p-type thermoelectric modules.</p> Graphical abstract <p></p>

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Advanced fabrication and contact strategies for high-performance MgAgSb thermoelectric materials

  • Cheng-Lun Hsin,
  • Cheng-Chu Tai,
  • Wan-Lu Wu,
  • Tzu-Kuan Yang,
  • Shao-Liang Cheng

摘要

This study explores the fabrication and characterization of MgAgSb thermoelectric composites to optimize performance through nanoparticle engineering and contact material selection. Adjusting the Mg3Sb2 to Ag3Sb nanopowder molar ratio to 2:1 reduced redundant Ag3Sb phases, which significantly enhancing thermoelectric efficiency. The effects of contact metals, including Al, Ag, and Ni, were evaluated using fabrication methods such as paste application, cold pressing, foil, and sputtering, showing their impact on the Seebeck coefficient. These results highlight the critical role of material composition and contact engineering in advancing thermoelectric materials. This approach provides a cost-effective strategy to improve MgAgSb composites in p-type thermoelectric modules.

Graphical abstract