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Enhancing photovoltaic performance through high-energy ball milling of Nb-doped TiO2 nanoparticles

  • Gideã Taques Tractz,
  • Gustavo Menim Cruz,
  • Edson Cezar Grzebielucka,
  • Estela dos Reis Crespan,
  • Sandra Regina Masetto Antunes,
  • Everson do Prado Banczek,
  • Paulo Rogério Pinto Rodrigues

摘要

It is demonstrated the capability of Nb combined with TiO2 to enhance charge transportation in solar systems; however, the particle size is still a barrier. This work aims to grind Nb:TiO2 particles, with a complete characterization to analyze the effect caused on particles by processing. Nb:TiO2 was produced by Pechini methodology, characterized by DLS, XRD, XPS, SEM images, and Mott-Schottky. It was verified the capability of grinding to reduce the particle size (~ 504 nm to ~ 54 nm) and change particle form. In a PV device, the milled particles have been able to produced a j = 10 mA cm−2.

Graphical abstract