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Surface and physicochemical characteristics of KSF-clay in a liquid esterification process: The boundaries between heterogeneous catalyst and precatalysts support

  • P. Rangel-Rivera,
  • B. Bachiller-Baeza,
  • A. Quiroga-Almaguer,
  • I. Galindo-Esquivel,
  • G. Rangel-Porras

摘要

The KSF-clay is a material that presents a high density of acidic active sites, ideal for being a heterogeneous acid catalyst with outstanding activity. For this study, KSF-clay was characterized by X-ray photoelectron spectroscopy and temperature-programmed desorption of ammonia. Additionally, studies of the adsorption of ethanol, propan-2-ol, and acetic acid molecules over KSF-clay surface to establish their thermal stability species were studied by diffuse reflectance infrared Fourier transform spectroscopy. The relationship between the properties of KSF-clay and the adsorption-interaction process with organic molecules is related to its performance as an acid catalyst.

Graphical abstract