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Chemically treated NiCo2O4 nanostructures with boric acid for the development of high-performance electrocatalytic materials for non-enzymatic ascorbic acid sensor

  • Sanjha Mangrio,
  • Aneela Tahira,
  • Ihsan Ali Mahar,
  • Ahmed Ali Hulio,
  • Muhammad Ali Bhatti,
  • Aqeel Ahmed Shah,
  • Umair Aftab,
  • Anjum Zehra Naqvi,
  • Nek Muhammad Shaikh,
  • Ayman Nafady,
  • Elmuez Dawi,
  • Abd Al Karim Haj Ismail,
  • Brigitte Vigolo,
  • Zafar Hussain Ibupoto

摘要

A method is presented in this paper for treating NiCo2O4 nanostructures with boric acid in an environmentally friendly and cost-effective manner. Boric acid was applied to chemically prepared NiCo2O4 nanostructures for different periods of time, including 30, 60, and 120 min. A variety of analytical techniques were used to examine the morphology, crystallinity, functional groups, and optical band gaps of the crystals. This resulted in the development of an electrochemical non-enzymatic ascorbic acid sensor using NiCo2O4 nanostructures treated with boric acid. After being infused with 0.5 M boric acid for 120 min, NiCo2O4 nanostructures demonstrated excellent performance for oxidizing AA in a phosphate buffer solution of pH 7.4. There was a wide linear range for non-enzymatic detection between 0.1 and 20 mM. We determined a limit of detection of approximately 0.003 mM and a limit of quantification of approximately 0.008 mM.

Graphical Abstract