Abstract <p>Compounds of antimony(III, V) were obtained: {[2,6-(ОMe)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)<sub>3</sub>]EtSb}I, [(2,6-OMe)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>]<sub>3</sub>SbO, [Sb(μ<sub>2</sub>-O)Cl(DMSO-О)]<sub><i>n</i></sub>, [(2,6-OMe)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>]<sub>3</sub>Sb(N<sub>3</sub>)<sub>2</sub>, (C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>SbBr<sub>2</sub>, [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>Sb(NCO)]<sub>2</sub>O⋅C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>, being by potential ferroelectrics. Temperature dependences of the permittivity of the compound were studied. According to dielectric measurements, it was established that for the compound [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>Sb(NCO)]<sub>2</sub>O⋅C<sub>4</sub>H<sub>8</sub>O<sub>2</sub> a phase transition is observed at a temperature of 164°C. The presence of hysteresis on the temperature dependence of ε' indicates a first-order phase transition.</p>

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Antimony Compounds as Potential Ferroelectric Materials

  • A. Yu. Milinskiy,
  • I. V. Egorova,
  • I. N. Nesina

摘要

Abstract

Compounds of antimony(III, V) were obtained: {[2,6-(ОMe)2C6H3)3]EtSb}I, [(2,6-OMe)2C6H3]3SbO, [Sb(μ2-O)Cl(DMSO-О)]n, [(2,6-OMe)2C6H3]3Sb(N3)2, (C6H5)3SbBr2, [(C6H5)3Sb(NCO)]2O⋅C4H8O2, being by potential ferroelectrics. Temperature dependences of the permittivity of the compound were studied. According to dielectric measurements, it was established that for the compound [(C6H5)3Sb(NCO)]2O⋅C4H8O2 a phase transition is observed at a temperature of 164°C. The presence of hysteresis on the temperature dependence of ε' indicates a first-order phase transition.