Abstract <p>A comparative study of the adsorption behavior of methane, ethane, propane and <i>n</i>-butane on the supermicroporous adsorbent ACW with a high micropore volume (1.44 cm<sup>3</sup>/g) and a wide distribution of pore sizes. The gas adsorption isotherms were measured by the volume–weight method at temperatures of 303, 313, 323, and 333 K in the pressure ranges of methane (0.1–40 MPa), ethane (0.01–3.8 MPa), propane (0.01–0.9 MPa), and <i>n</i>-butane (0.01–0.19 MPa). The IAST method was used to calculate the adsorption of binary mixtures CH<sub>4</sub>/C<sub>2</sub>H<sub>6</sub>, CH<sub>4</sub>/C<sub>3</sub>H<sub>8</sub>, and CH<sub>4</sub>/H<sub>10</sub> with component contents of 98/2, 95/5, 92/8, and 90/10 mol %, respectively. The potential selectivity of the ACW adsorbent in adsorption gas separation processes was assessed for their further use.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Adsorption of Lower Alkanes CH4, C2H6, C3H8, and n-C4N10 and Their Mixtures on Highly Active Microporous Carbon Adsorbent

  • S. D. Artamonova,
  • A. A. Pribylov,
  • A. E. Grinchenko,
  • A. A. Fomkin,
  • I. E. Menshchikov,
  • A. V. Shkolin

摘要

Abstract

A comparative study of the adsorption behavior of methane, ethane, propane and n-butane on the supermicroporous adsorbent ACW with a high micropore volume (1.44 cm3/g) and a wide distribution of pore sizes. The gas adsorption isotherms were measured by the volume–weight method at temperatures of 303, 313, 323, and 333 K in the pressure ranges of methane (0.1–40 MPa), ethane (0.01–3.8 MPa), propane (0.01–0.9 MPa), and n-butane (0.01–0.19 MPa). The IAST method was used to calculate the adsorption of binary mixtures CH4/C2H6, CH4/C3H8, and CH4/H10 with component contents of 98/2, 95/5, 92/8, and 90/10 mol %, respectively. The potential selectivity of the ACW adsorbent in adsorption gas separation processes was assessed for their further use.