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Synthesis and Examination of the ZrBDC Functionalized Metal–Organic Framework Structure for Carbon Dioxide Adsorption

  • O. E. Mel’nik,
  • A. E. Grinchenko,
  • A. A. Fomkin,
  • A. V. Shkolin,
  • M. K. Knyazeva,
  • I. E. Men’shchikov

摘要

Abstract

In the present work, the ZrBDC metal–organic framework structure was synthesized; it is characterized by the high specific surface area (1330 m2/g) and micropore volume (0.57 cm3/g) and demonstrated sufficient thermal resistance (up to 200°C). The prepared sample exhibited a high adsorption capacity with respect to carbon dioxide adsorption (13.5 mmol/g), and this fact suggests that it is a promising adsorbent for accumulation of carbon dioxide.