Scholarlink

Abstract <p>Among the different approaches for CO<sub>2</sub> emanation alleviation and climate change mitigation, recycling CO<sub>2</sub> into added-value products through electrochemical reduction is promising. This study highlights the conversion of CO<sub>2</sub> to formate using a composite electrode of Pb-graphite in an H-type cell. Different composite electrodes with variable wt % of Pb and graphite were investigated. Electrode characterization using energy dispersive X-ray and Scanning electron microscope provided a porous surface with partially flaky crack morphology and a homogeneous distribution of Pb in the graphite matrix. Absorption of CO<sub>2</sub> by 0.1 M KHCO<sub>3</sub> at 25°C and 1 atm provided a value of 1.434 g/L (30.66 mol/L). Adsorption of the dissolved CO<sub>2</sub> by 50 wt % Pb electrodes demonstrated a saturation capacity of 590 mg/g. Cyclic voltammetry showed a distinct reduction peak of CO<sub>2</sub> at –0.62 V (vs. Ag/AgCl). This peak has increased with an increased amount of absorbed CO<sub>2</sub> in 0.1 M KHCO<sub>3</sub>. Linear Sweep Voltammetry provided an irreversible conversion of CO<sub>2</sub> to formate with a peak current of 32.5 mA at a scan rate of 0.1 V/s and 1 M KCO<sub>3</sub>. Electrode kinetic analysis proved a Butler–Volmer reduction constant of <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11826_2025_9166_Article_IEq1.gif" Format="GIF" Height="17" Rendition="HTML" Resolution="72" Type="Linedraw" Width="64" /> </InlineMediaObject> <EquationSource Format="TEX">\(\beta = 0.62\)</EquationSource> <!--PhysChB2570020Alsaida-m1--> </InlineEquation> at 298 K, leading to a differential change in reaction constant with the potential 77.89 <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11826_2025_9166_Article_IEq2.gif" Format="GIF" Height="17" Rendition="HTML" Resolution="72" Type="Linedraw" Width="56" /> </InlineMediaObject> <EquationSource Format="TEX">\({{{\text{V}}}^{{ - 1}}}{{\;}}{{{\text{s}}}^{{ - 1}}}\)</EquationSource> <!--PhysChB2570020Alsaida-m2--> </InlineEquation>. The corresponding current efficiency was varied with a variation of KHCO<sub>3</sub> concentration to yield a value of 96% obtained using 1 M KHCO<sub>3</sub> and 25°C. Therefore, the composite Pb-graphite electrode demonstrated high surface area, minimum mass transfer, and diffusion resistance of the dissolved CO<sub>2</sub> to the electrode surface.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Electrocatalytic Conversion of CO2 to Formate on a Pb–Graphite Composite Electrode

  • 期刊论文

  • 发表日期：

    2025年4月1日

查看全文
  • Basel Al-Saida

摘要

Abstract

Among the different approaches for CO2 emanation alleviation and climate change mitigation, recycling CO2 into added-value products through electrochemical reduction is promising. This study highlights the conversion of CO2 to formate using a composite electrode of Pb-graphite in an H-type cell. Different composite electrodes with variable wt % of Pb and graphite were investigated. Electrode characterization using energy dispersive X-ray and Scanning electron microscope provided a porous surface with partially flaky crack morphology and a homogeneous distribution of Pb in the graphite matrix. Absorption of CO2 by 0.1 M KHCO3 at 25°C and 1 atm provided a value of 1.434 g/L (30.66 mol/L). Adsorption of the dissolved CO2 by 50 wt % Pb electrodes demonstrated a saturation capacity of 590 mg/g. Cyclic voltammetry showed a distinct reduction peak of CO2 at –0.62 V (vs. Ag/AgCl). This peak has increased with an increased amount of absorbed CO2 in 0.1 M KHCO3. Linear Sweep Voltammetry provided an irreversible conversion of CO2 to formate with a peak current of 32.5 mA at a scan rate of 0.1 V/s and 1 M KCO3. Electrode kinetic analysis proved a Butler–Volmer reduction constant of \(\beta = 0.62\) at 298 K, leading to a differential change in reaction constant with the potential 77.89 \({{{\text{V}}}^{{ - 1}}}{{\;}}{{{\text{s}}}^{{ - 1}}}\) . The corresponding current efficiency was varied with a variation of KHCO3 concentration to yield a value of 96% obtained using 1 M KHCO3 and 25°C. Therefore, the composite Pb-graphite electrode demonstrated high surface area, minimum mass transfer, and diffusion resistance of the dissolved CO2 to the electrode surface.