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Kinetics of the Thermal Decomposition of Methyl Derivatives of 7H-Difurazanofuxanoazepine and 7H-Tryfurasanoazepine

  • A. I. Kazakov,
  • D. B. Lempert,
  • A. V. Nabatova,
  • E. L. Ignatieva,
  • D. V. Dashko,
  • V. V. Raznoschikov,
  • L. S. Yanovskiy

摘要

Abstract

The thermal stability of N-methyl derivatives of 7H-difurazanofuroxanoazepine and 7H-trifurazanoazepine in the nonisothermal and isothermal modes is studied. The formal-kinetic laws of the decomposition and temperature dependencies of the reaction rate constants are determined. The thermal stability of methyl, propargyl, cyanomethyl, allyl, and amine derivatives of azepines is compared.