Influence of Self-Heating on the Kinetics of an Exothermal Reaction under Isothermal Conditions
摘要
Abstract
Estimates are made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, whose values are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.