Synthesis and Properties of Hydrogenated Metathesis Oligonorbornene

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发表日期：

2024年12月1日

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V. R. Nazemutdinova,
A. I. Wozniak,
S. O. Ilyin,
A. A. Morontsev,
M. V. Bermeshev

摘要

Abstract

Metathesis oligomerization of norbornene in the presence of the first-generation Grubbs catalyst and ethylene used as a chain transfer agent yielded an oligomeric product, which was then hydrogenated over a palladium catalyst. After oligomerization and modification, the yield of the products was over 80 and 90%, respectively. The structure of the oligomers was confirmed by ¹H and ¹³C NMR spectroscopy. Thermal and rheological properties of the obtained oligomer have been studied in detail.