Abstract— <p>In this paper, acrylic acid based light-responsive molecularly imprinted polymers were synthesized for the molecular recognition of methylene blue with light regulation performance, enriching their application environments. The template-rebinding/-release studies of the molecularly imprinted polymers showed that their affinity of the adsorption recognition sites were successfully regulated by the <i>cis</i>-<i>trans</i> isomerization of the azo group in the polymers. Rebinding isotherms and rebinding kinetics show that the adsorption of methylene blue by imprinted materials conforms to the single-layer chemical adsorption and pseudo-second-order kinetic model.</p>

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Photo-Responsive Azobenzene-Containing Molecularly Imprinted Copolymers: Synthesis and Properties

  • Yujuan Wu,
  • Jiajun Zuo,
  • Haoqian Wang,
  • Heyuan Song,
  • Donghong Yu,
  • Nong Wang

摘要

Abstract—

In this paper, acrylic acid based light-responsive molecularly imprinted polymers were synthesized for the molecular recognition of methylene blue with light regulation performance, enriching their application environments. The template-rebinding/-release studies of the molecularly imprinted polymers showed that their affinity of the adsorption recognition sites were successfully regulated by the cis-trans isomerization of the azo group in the polymers. Rebinding isotherms and rebinding kinetics show that the adsorption of methylene blue by imprinted materials conforms to the single-layer chemical adsorption and pseudo-second-order kinetic model.