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Abstract <p>The regio- and stereoselective synthesis of new (<i>Z</i>)-selenocyanatoacrylamides containing <i>N</i>-alkylamide groups and cyclic amide substituents (yields 76–93%) by the reaction of potassium selenocyanate with 3-trimethylsilyl-2-propynamides was developed. The reaction proceeded in aqueous acetonitrile in the presence of ammonium chloride and was accompanied by a desilylation process.</p>

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Regio- and Stereoselective Synthesis of New (Z)-Selenocyanatoacrylamides

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  • 发表日期：

    2025年11月1日

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  • M. V. Andreev,
  • V. A. Potapov,
  • M. V. Musalov,
  • L. I. Larina

摘要

Abstract

The regio- and stereoselective synthesis of new (Z)-selenocyanatoacrylamides containing N-alkylamide groups and cyclic amide substituents (yields 76–93%) by the reaction of potassium selenocyanate with 3-trimethylsilyl-2-propynamides was developed. The reaction proceeded in aqueous acetonitrile in the presence of ammonium chloride and was accompanied by a desilylation process.