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Abstract <p>Reactions of 1,1′-biadamantanes in nitric acid medium in the presence of nitrogen nucleophiles afforded a number of symmetrical difunctional derivatives. Reactions of 1,1′-biadamantane-3,3′-diols with carbon nucleophiles were carried out in sulfuric acid medium. A series of new tetra- and hexasubstituted functionalized 1,1′-biadamantane derivatives were synthesized in the system H<sub>2</sub>SO<sub>4</sub>–HNO<sub>3</sub>.</p>

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Functionalization of 1,1′-Biadamantanes in Acidic Medium

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年10月1日

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  • E. A. Ivleva,
  • D. V. Zolotarev,
  • Yu. E. Khatmullina,
  • A. K. Shiryaev,
  • Yu. N. Klimochkin

摘要

Abstract

Reactions of 1,1′-biadamantanes in nitric acid medium in the presence of nitrogen nucleophiles afforded a number of symmetrical difunctional derivatives. Reactions of 1,1′-biadamantane-3,3′-diols with carbon nucleophiles were carried out in sulfuric acid medium. A series of new tetra- and hexasubstituted functionalized 1,1′-biadamantane derivatives were synthesized in the system H2SO4–HNO3.