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Synthesis of α-Glycol Monoallyl Ethers

  • G. M. Talybov

摘要

Abstract

Allyl chloromethyl and allyl 1-chloroethyl ethers reacted with carbonyl compounds in the presence of fine zinc shavings and a catalytic amount of HgCl2 in a mixture of benzene, ethyl acetate, and HMPA (10:5:1) under nitrogen to give the corresponding α-glycol monoallyl ethers in up to 68.1% yield.